CHEM3037 Advanced Inorganic Chemistry for –BSc and MChem Year 3 (single honours)
Aims and Objectives
The module aims to complete the coverage of core inorganic chemistry, by revising and extending topics met in years 1 and 2, and also introduces several new themes. Included are topics in materials and organometallic chemistry, pigments, f-block chemistry, and the applications of UV/visible spectroscopy and quadrupolar NMR nuclei to the study of Inorganic systems. At the end of this module the student should have a good overview of the major areas of modern Inorganic chemistry and have mastered the application of the key physical techniques to study Inorganic compounds. In the first section of the module students are expected to develop an understanding of spectroscopic techniques applied directly to Inorganic systems. Topics covered in this section are: UV/visible spectroscopy, quadrupole NMR and Electron Paramagnetic Resonance (EPR). The aim of f-block section of the module is to introduce f-element chemistry. The basics of general f-element chemistry (discovery, properties of the f-orbitals, electron configurations) are introduced before discussing in detail the general, photophysical, magnetic and chemical properties of the 4f elements (lanthanoids). Finally the physical and chemical properties of the 5f-elements (the actinoid series) and differences between 4f and 5f are discussed. The aim of the organometallics section of the module is to provide a reintroduction to organometallic chemistry and to expand upon the concepts previously encountered to consider the chemistry of transition metal compounds with the ?-bonded ligands.
Having successfully completed this module you will be able to:
- Determine ground state term symbols for any d-electron configuration
- Describe bonding models that can be applied to a consideration of the properties of transition metal organometallic species with a wide range of ligands.
- Determine ?O and B from Tanabe-Sugano Diagrams
- Interpret simple EPR spectra
- Construct correlation diagrams
- Interpret trends in the oxidation states of Lanthanides
- Determine full Russell-Saunders ground terms for Lanthanides
- Calculate effective magnetic moments for lanthanide compounds using the J-moment method
- Describe the differences between 4f and 5f orbitals
- Qualitatively discuss the organometallic chemistry of transition metal compounds with p-bonded ligands in terms of their synthesis, reactivities and uses in catalysis.
The assignment of UV-visible spectra of transition metal complexes including both d-d ( Russell-Saunders coupling and Orgel diagrams) and charge transfer spectra will be introduced. The key features of quadrupolar NMR nuclei and their application to study Inorganic systems will be described. The key features of the chemistry of the f-block elements (lanthanides and actinides) will be described along with a coverage of f-f spectra of the lanthanide elements and the optical and magnetic properties of the solids. Transition metal organometallic chemistry from CHEM 2009/2016 will be extended to describe p-ligands (alkenes, alkynes, allyls, cyclopentaidienyls, arenes etc.), carbennes and carbynes, key reactions and catalytic cycles and behaviours.
Learning and Teaching
Teaching and learning methods
|Preparation for scheduled sessions||32|
|Wider reading or practice||40|
|Practical classes and workshops||6|
|Total study time||150|
Resources & Reading list
M. Bochmann. Organometallics I.
A.K. Brisdon. Inorganic Spectroscopic Methods.
N. Kaltsoyannis and P Scott. The f elements.
M. Bochmann. Organometallics II.
C E Housecroft (1999). The Heavier d-block Metals.
|Examination (2 hours)||100%|
|Examination (2 hours)||100%|