Research Group: Electrochemistry
Southampton has an established world-class reputation in electrochemistry research. Electrochemistry is a broad subject covering all areas of charge transfer reactions at interfaces and impacts on daily life in many immediate ways from corrosion and energy storage, through water treatment and purification, clean energy generation and environmental monitoring to medical diagnostics and electrodeposition.
Currently Active: Yes
Group Overview
The Electrochemistry Research Group has research programmes in electrochemical approaches to energy conversion and storage including research in tfuel cells (operando studies of fuel cell catalysts, new catalyst materials, membranes), lithium batteries (novel 3D battery structures and electrolytes, modelling of battery performance), redox flow batteries and supercapacitors.
Our work in energy is underpinned by in-situ and ex-situ studies of well characterised systems, providing fundamental insights into electrocatalysis. Our work on the development and application of high-throughput methodologies in electrochemistry has been applied to functional materials discovery for a wide range of applications and for electrode modification for applications in electroanalysis, biosensors and biofuel cells. This work has resulted in a very successful spin-out company, Ilika, with more fundamental work still being pursued within the School.
The Electrochemistry Research Group is active in the area of templated electrodeposition of nanomaterials and the applications of nanomaterials, particularly in plasmonics and metamaterials, with internationally leading programmes. Templated electrodeposition technologies, pioneered in Southampton, offer effective routes to novel nanostructures which have the ability to produce large quantities, or areas, of material at reasonable cost. Our earlier work is being commercialised by Nanotecture, a spin-out company in the field of energy storage.
We are currently employing nanostructured plasmonic structures as surfaces for surface enhanced Raman spectroscopy (SERS) to develop sensitive, specific sensors for healthcare, environmental and security applications including point-of care diagnostics. Highly structured electrode surfaces are also employed in the development of sensors for a wide variety of analytical applications, including deep-ocean sensors and the characterisation of ultrasonic devices. We also have active research programmes in acustoelectrochemistry, sonoluminescence, scanning electrochemical microscopy, materials electrochemistry and solid state electrochemistry.
Publications
Selected publications associated with this group from the University of Southampton's electronic library (e-prints):
Key Publications
Staff
Members of staff associated with this group:

Professor Phil N Bartlett
Professor
Dr Peter R Birkin
Senior Lecturer
Dr Guy Denuault
Senior Lecturer
Dr Nuria Garcia-Araez
Lecturer
Professor Brian E Hayden
Professor
Dr Andrew L Hector
Senior Lecturer
Professor John R Owen
Professor
Professor Derek Pletcher
Emeritus Professor
Professor Andrea E Russell
Professor
Research projects
Research projects associated with this group:
Electrolytic Engineering Approaches to Harvest Algae for Liquid Biofuels
Pletcher: Batteries for large scale energy storage
Bartlett: Bioelectrochemistry and Biosensors
Pletcher: Effluent and Water Treatment
Pletcher: Electrocatalysis and Fuel Cells
Russell: Electrocatalysts for PEM and Direct Methanol Fuel Cells
Denuault: Electrochemical sensors for Oceanography
Bartlett: Electrodeposition in Supercritical Fluids
Owen: Fabrication methods for 3D batteries
Owen: High throughput discovery of electrochemical materials for energy conversion and storage
Hayden: High Throughput Synthesis and Screening of Electrocatalysts
Hayden: HT Screening of Functional Oxides
Hayden: HT Screening of Corrosion Resistant Materials
Hayden: High Throughput Synthesis and Screening of Hydrogen Storage Alloys
Birkin: Hydrodynamic Modulated Voltammetry (HMV)
Russell: Infrared at Surfaces: RAIRS and SEIRAS
Birkin: Luminescence and High speed Imaging
Hector: Metal nitride nanoparticles
Hector: Nanocrystalline metal nitride materials
Bartlett & Nandhakumar: Nanostructured Materials
Owen: Nanostructured Electrode materials for batteries and supercapacitors
Denuault: Numerical simulations of electrode reactions
Hector: Precursor chemistry for materials deposition
Hector: Pyrochlore materials containing Bi3+
Denuault: Scanning electrochemical microscopy (SECM)
Bartlett & Nandhakumar: Self Assembly
Birkin: Single Bubble Sonoluminescence
Hector: Sol-gel chemistry to nitride materials
Hayden: Surface Electrochemistry
Bartlett & Nandhakumar: Surface Enhanced Raman Spectroscopy
Russell: Surface Enhanced Raman Spectroscopy
Birkin: Surface Erosion/Corrosion
Hayden: Surface Science Model Heterogeneous Catalysis
Russell: X-ray Absorption Spectroscopy of Catalysts and Electrocatalysts