Solid state and organometallic chemistry | CHEM2032

Module overview

In this module you will learn about the fundamental theory of bonding in solids – band theory, and show how this can be used to understand the optical, magnetic and optical properties of solid phase materials. You will also be taught about X-ray diffraction, and how this can be used to determine the structure of crystalline solids. We will also attempt to understand the links between structure and properties. The module will also expand on your knowledge of organometallic compounds, considering their use in catalytic cycles, and introducing metallocene ligands.

Linked modules

Pre-requisite(s): CHEM2026 and (CHEM2035 or CHEM3053 or NATS2004)

Aims and Objectives

Learning Outcomes

Knowledge and Understanding

Having successfully completed this module, you will be able to demonstrate knowledge and understanding of:

Describe the organometallic chemistry of transition metals with a broad range of pi-ligands.
Draw catalytic cycles to describe a range of reactions mediated by transition metal organometallic species.
Explain and analyse X-ray diffraction data, including indexing cubic diffraction patterns, and carry out calculations of lattice parameters and parameters related to the electronic structure of solid state materials.
Explain phenomena in solids including defect structures, various types of conductivity, and magnetic and optical properties, within the context of band theory
Sketch aspects of solid state structure (unit cells, polyhedra, lattice planes, how diffraction arises, unit cells, not previously encountered) and electronic structure (band diagrams, junctions).
Present the results of a practical investigation in a concise manner.

Subject Specific Practical Skills

Having successfully completed this module you will be able to:

Interpret data from a range of physical techniques to characterise inorganic compounds.
Set up glassware and apparatus to conduct experiments in Inorganic Chemistry.

Syllabus

X-ray diffraction and structure: Crystal lattices and symmetry; Modelling solids as connected polyhedral – silicates, spinel, perovskite; Diffraction of X-rays by crystals; Indexing of diffraction data; Dependence of intensity on structure factor.

Bonding and properties of solids: Basic band theory in semiconductors, metals and insulators; Doping and compound semiconductor trends; Conductors transparent conductors and superconductors; Optical properties of solids; Magnetism in perovskites, spinels and transition metal oxides; Defects and ionic conductivity.

Organometallic chemistry: Transition metal organometallic chemistry with π-ligands; Multiply-bonded ligands; Key reactions and catalytic cycles and behaviours.

Learning and Teaching

Teaching and learning methods

Lectures, small group tutorials and laboratory sessions.

Study time
Type	Hours
Lecture	24
Completion of assessment task	24
Practical	29
Tutorial	5
Revision	10
Preparation for scheduled sessions	58
Total study time	150

Resources & Reading list

Textbooks

C. E. Housecroft and A. G. Sharpe (2018). Inorganic Chemistry.

Lesley E. Smart and Elaine A. Moore. Solid State Chemistry: An Introduction.

Assessment

Assessment strategy

Final exam, tutorials and laboratory marks.

Summative

This is how we’ll formally assess what you have learned in this module.

Breakdown
Method	Percentage contribution
Examination	60%
Laboratory practicals	30%
Assessed Tutorials	10%

Referral

This is how we’ll assess you if you don’t meet the criteria to pass this module.

Breakdown
Method	Percentage contribution
Examination	100%

Repeat Information

Repeat type: Internal & External