Solid State and Organometallic Chemistry

Learning Outcomes

Knowledge and Understanding

Having successfully completed this module, you will be able to demonstrate knowledge and understanding of:

• Describe the organometallic chemistry of transition metals with a broad range of pi-ligands.
• Explain and analyse X-ray diffraction data, including indexing cubic diffraction patterns, and carry out calculations of lattice parameters and parameters related to the electronic structure of solid state materials.
• Sketch aspects of solid state structure (unit cells, polyhedra, lattice planes, how diffraction arises, unit cells, not previously encountered) and electronic structure (band diagrams, junctions).
• Draw catalytic cycles to describe a range of reactions mediated by transition metal organometallic species.
• Explain phenomena in solids including defect structures, various types of conductivity, and magnetic and optical properties, within the context of band theory
• Present the results of a practical investigation in a concise manner.

Subject Specific Practical Skills

Having successfully completed this module you will be able to:

• Interpret data from a range of physical techniques to characterise inorganic compounds.
• Set up glassware and apparatus to conduct experiments in Inorganic Chemistry.

X-ray diffraction and structure: Crystal lattices and symmetry; Modelling solids as connected polyhedral – silicates, spinel, perovskite; Diffraction of X-rays by crystals; Indexing of diffraction data; Dependence of intensity on structure factor.

Bonding and properties of solids: Basic band theory in semiconductors, metals and insulators; Doping and compound semiconductor trends; Conductors transparent conductors and superconductors; Optical properties of solids; Magnetism in perovskites, spinels and transition metal oxides; Defects and ionic conductivity.

Organometallic chemistry: Transition metal organometallic chemistry with π-ligands; Multiply-bonded ligands; Key reactions and catalytic cycles and behaviours.

Teaching and learning methods

Lectures, small group tutorials and laboratory sessions.

Resources & Reading list

Textbooks

C. E. Housecroft and A. G. Sharpe (2018). Inorganic Chemistry.

Lesley E. Smart and Elaine A. Moore. Solid State Chemistry: An Introduction.

Assessment strategy

Final exam, tutorials and laboratory marks.

Summative

This is how we’ll formally assess what you have learned in this module.

Referral

This is how we’ll assess you if you don’t meet the criteria to pass this module.

Repeat Information

Repeat type: Internal & External