Dr Ilya Kuprov

Associate Professor of Chemical Physics

Related links: Personal homepage

Dr Ilya Kuprov is Associate Professor of Chemical Physics within Chemistry at the University of Southampton.

Ilya Kuprov is an Associate Professor of Chemical Physics, having previously been an EPSRC Research Fellow (2009 - 2014), a Lecturer in Physical Chemistry at the University of Durham (2007 - 2009), and a Fellow by Examination at Magdalen College, Oxford (2005 - 2010).

The area of expertise of Dr Kuprov's research group is Quantum Theory: we are working on quantum mechanical models of magnetic processes, such as those encountered in Nuclear Magnetic Resonance, Electron Spin Resonance, Magnetic Resonance Imaging, Spin Chemistry and related areas. Applications of our research span a huge range of topics, from photosynthesis to parallel computing to quantum control theory. We always have undergraduate and PhD projects available in all of those areas, please get in touch if you are interested.

Research

Publications

Contact

Research interests

The focus of Dr Kuprov's research group is on theoretical and computational methods of quantum theory. Major recent results are:

1. The development and implementation of a pattern-matching processor for the automated processing of quantum decoherence theory equations. The resulting processor turned out to be superior to human intelligence in what was traditionally the domain of the latter - analytical derivations and transformations.

2. The discovery and implementation of polynomially scaling spin dynamics simulation algorithms, which eliminated decades-old bottlenecks and enabled quantum simulations of dynamics in large coupled spin systems. The resulting open-source software package (http://spindynamics.org) runs full quantum mechanical simulations of systems with over 50 spins in minutes - something that was unthinkable just three years ago.

The recent highlights of collaborative research are:

1. The discovery of the first 'chemical compass' molecule, which changes its properties when rotated with respect to the Earth's magnetic field. This has major implications in our understanding of animal navigation, specifically the mechanisms of 'magnetic sense' exhibited by migratory birds.

2. The development of paramagnetic pH-responsive contrast agents for early-stage MRI (magnetic resonance imaging) cancer diagnostics. Because cancer tissue is frequently more acidic than healthy tissue, these molecules provide tumour-specific contrast in the resulting images.

The current ongoing research includes:

1. The development of "direct" magnetic resonance molecular structure refinement tools, where atomic coordinates are optimized directly against the experimental spectra. This was made possible by the above mentioned efficient spin dynamics simulation algorithms.

2. The development of standardized markup languages for the description of spin systems and experiments. Inputs used by the existing spectrometers and simulation software are historically convoluted ad hoc schemes, and there is a consensus in the community that a central standard format is required.

3. Theoretical research into the structures and magnetic properties of lanthanide-based paramagnetic MRI (magnetic resonance imaging) contrast agents used in cancer diagnostics.

4. A systematic search for long-lived states in large spin systems for use as magnetization storage pools in magnetic resonance spectroscopy.

Research group

Computational Systems Chemistry

Research project(s)

Kuprov: Decoherence-free subspaces in large quantum spin systems

Kuprov: Highly efficient quantum spin dynamics simulation algorithms

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Key Publications

Maeda, K., Henbest, K. B., Cintolesi, F., Kuprov, I., Rodgers, C. T., Liddell, P. A., ... Hore, P. J. (2008). Chemical compass model of avian magnetoreception. Nature, 453(7193), 387-390. DOI: 10.1038/nature06834
Khan, F., Kuprov, I., Craggs, T. D., Hore, P. J., & Jackson, S. E. (2006). 19F NMR studies of the native and denatured states of green fluorescent protein. Journal of the American Chemical Society, 128(33), 10729-10737. DOI: 10.1021/ja060618u
Kuprov, I., Wagner-Rundell, N., & Hore, P. J. (2007). Polynomially scaling spin dynamics simulation algorithm based on adaptive state-space restriction. Journal of Magnetic Resonance, 189(2), 241-250. DOI: 10.1016/j.jmr.2007.09.014
Hogben, H. J., Krzystyniak, M., Charnock, G. T. P., Hore, P. J., & Kuprov, I. (2011). Spinach – a software library for simulation of spin dynamics in large spin systems. Journal of Magnetic Resonance, 208(2), 179-194. DOI: 10.1016/j.jmr.2010.11.008
de Fouquieres, P., Schirmer, S. G., Glaser, S. J., & Kuprov, I. (2011). Second order gradient ascent pulse engineering. Journal of Magnetic Resonance, 212(2), 412-417. DOI: 10.1016/j.jmr.2011.07.023

Articles

Sternberg, U., Witter, R., Kuprov, I., Lamley, J. M., Oss, A., Lewandowski, J. R., & Samoson, A. (2018). ¹H line width dependence on MAS speed in solid state NMR – comparison of experiment and simulation. Journal of Magnetic Resonance, 291, 32-39. DOI: 10.1016/j.jmr.2018.04.003
Worswick, S. G., Spencer, J. A., Jeschke, G., & Kuprov, I. (2018). Deep neural network processing of DEER data. Science Advances, 4(8), 1-17. [eaat5218]. DOI: 10.1126/sciadv.aat5218
Goodwin, D. L., Myers, W. K., Timmel, C. R., & Kuprov, I. (2018). Feedback control optimisation of ESR experiments. Journal of Magnetic Resonance, 297, 9-16. DOI: 10.1016/j.jmr.2018.09.009
Duong, N. T., Kuprov, I., & Nishiyama, Y. (2018). Indirect detection of ¹⁰B (I = 3) overtone NMR at very fast magic angle spinning. Journal of Magnetic Resonance, 291, 27-31. DOI: 10.1016/j.jmr.2018.04.004
Suturina, E., Mason, K., Geraldes, C. F. G. C., Chilton, N. F., Parker, D., & Kuprov, I. (2018). Lanthanide‐induced relaxation anisotropy. Physical Chemistry Chemical Physics, 2018(20), 17676-17686. DOI: 10.1039/C8CP01332B
Robertson, G. P., Odell, B., Kuprov, I., Dixon, D. J., & Claridge, T. D. W. (2018). Measuring spin relaxation rates using satellite exchange NMR spectroscopy. Angewandte Chemie International Edition, 57(25), 7498-7502. DOI: 10.1002/anie.201801322
Hofman, G-J., Ottoy, E., Light, M., Kieffer, B., Kuprov, I., Martins, J. C., ... Linclau, B. (2018). Minimising conformational bias in fluoroprolines through vicinal difluorination. Chemical Communications, 54(40), 5118-5121. DOI: 10.1039/C8CC01493K
Saywell, J. C., Kuprov, I., Goodwin, D., Carey, M. S., & Freegarde, T. (2018). Optimal control of mirror pulses for cold-atom interferometry. Physical Review A, 98, 1-9. [023625]. DOI: 10.1103/PhysRevA.98.023625
Aguilar, J. A., Belda, R., Gaunt, B. R., Kenwright, A. M., & Kuprov, I. (2018). Separating the coherence transfer from chemical shift evolution in high-resolution Pure Shift COSY NMR. Magnetic Resonance in Chemistry, 56(10), 969-975. DOI: 10.1002/mrc.4727
Shishmarev, D., Fontenelle, C. Q., Kuprov, I., Linclau, B., & Kuchel, P. W. (2018). Transmembrane exchange of fluorosugars: Characterization of red cell GLUT1 kinetics using ¹⁹F NMR. Biophysical Journal. DOI: 10.1016/j.bpj.2018.09.030
Parker, D., Kuprov, I., Suturina, E., Mason, K., & Geraldes, C. F. G. C. (2017). Beyond Bleaney's theory: experimental and theoretical analysis of periodic trends in lanthanide induced chemical shift. Angewandte Chemie International Edition. DOI: 10.1002/anie.201706931
Richert, S., Cremers, J., Kuprov, I., Peeks, M. D., Anderson, H. L., & Timmel, C. R. (2017). Constructive quantum interference in a bis-copper six-porphyrin nanoring. Nature Communications, 8, [14842]. DOI: 10.1038/ncomms14842
Guduff, L., Allami, A. J., van Heijenoort, C., Dumez, J-N., & Kuprov, I. (2017). Efficient simulation of ultrafast magnetic resonance experiments. Physical Chemistry Chemical Physics. DOI: 10.1039/C7CP03074F
Goura, J., Colacio, E., Herrera, J. M., Suturina, E. A., Kuprov, I., Lan, Y., ... Chandrasekhar, V. (2017). Heterometallic Zn3Ln3 ensembles containing (μ6-CO3) ligand and triangular disposition of Ln3+ ions: Analysis of single-molecule toroic (SMT) and single-molecule magnet (SMM) behavior. Chemistry - A European Journal, 23(65), 16621-16636. DOI: 10.1002/chem.201703842
Kuprov, I. (2017). Large‐scale NMR simulations in liquid state: a tutorial. Magnetic Resonance in Chemistry, 56(6). DOI: 10.1002/mrc.4660
Jarvis, J., Haies, I., Lelli, M., Rossini, A., Kuprov, I., Carravetta, M., & Williamson, P. (2017). Measurement of 14N Quadrupole Couplings in Biomolecular Solids Using Indirect-Detection 14N Solid-State NMR with DNP. Chemical Communications.
Suturina, E., Häussinger, D., Zimmermann, K., Garbuio, L., Yulikov, M., Jeschke, G., & Kuprov, I. (2017). Model-free extraction of spin label position distributions from pseudocontact shift data. Chemical Science, 1-12. DOI: 10.1039/C6SC03736D
Mason, K., Rogers, N. J., Suturina, E., Kuprov, I., Aguilar, J. A., Batsanov, A. S., ... Parker, D. (2017). PARASHIFT Probes:: solution NMR and X-ray structural studies of macrocyclic ytterbium and yttrium complexes. Inorganic Chemistry, 56(7), 4028-4038. DOI: 10.1021/acs.inorgchem.6b02291
Richert, S., Kuprov, I., Peeks, M. D., Suturina, E., Cremers, J., Anderson, H. L., & Timmel, C. R. (2017). Quantifying the exchange coupling in linear copper porphyrin oligomers. Physical Chemistry Chemical Physics. DOI: 10.1039/c7cp01787a
Vonci, M., Mason, K., Suturina, E., Frawley, A. T., Worswick, S. G., Kuprov, I., ... Chilton, N. F. (2017). Rationalization of anomalous pseudocontact shifts and their solvent dependence in a series of C3-symmetric lanthanide complexes. Journal of the American Chemical Society, 139(40), 14166-14172. DOI: 10.1021/jacs.7b07094
Guduff, L., Kuprov, I., van Heijenoort, C., & Dumez, J-N. (2017). Spatially encoded 2D and 3D diffusion-ordered NMR spectroscopy. Chemical Communications, 53(4), 701-704. DOI: 10.1039/C6CC09028A
Manukovsky, N., Feintuch, A., Kuprov, I., & Goldfarb, D. (2017). Time domain simulation of Gd3+-Gd3+ distance measurements by EPR. The Journal of Chemical Physics, 147(4). DOI: 10.1063/1.4994084
Kuprov, I. (2016). Fokker-Planck formalism in magnetic resonance simulations. Journal of Magnetic Resonance, 270, 124-135. DOI: 10.1016/j.jmr.2016.07.005
Goodwin, D., & Kuprov, I. (2016). Modified Newton-Raphson GRAPE methods for optimal control of quantum systems. The Journal of Chemical Physics, 144, 204107. DOI: 10.1063/1.4949534
Suturina, E., & Kuprov, I. (2016). Pseudocontact shifts from mobile spin labels. Physical Chemistry Chemical Physics, 18(38), 26412-26422. DOI: 10.1039/C6CP05437D
Panduwawala, T. D., Josa-Culleré, L., Kuprov, I., Odell, B., Moloney, M. G., & Claridge, T. D. W. (2016). Scalar cross-relaxation detected in the NOESY spectra of oxazolidines and thiazolidines. Journal of Organic Chemistry, 81(10), 4142-4148. DOI: 10.1021/acs.joc.6b00458
Raybould, T. A., Fedotov, V. A., Papasimakis, N., Kuprov, I., Youngs, I. J., Chen, W. T., ... Zheludev, N. I. (2016). Toroidal circular dichroism. Physical Review B, 94(3), 1-5. DOI: 10.1103/PhysRevB.94.035119
Orton, H. W., Kuprov, I., Loh, C-T., & Otting, G. (2016). Using paramagnetism to slow down nuclear relaxation in protein NMR. The Journal of Physical Chemistry Letters, 7(23), 4815-4818. DOI: 10.1021/acs.jpclett.6b02417
Haies, I. M., Jarvis, J. A., Bentley, H., Heinmaa, I., Kuprov, I., Williamson, P. T. F., & Carravetta, M. (2015). 14N overtone NMR under MAS: signal enhancement using symmetry-based sequences and novel simulation strategies. Physical Chemistry Chemical Physics, 17(9), 6577-6587. DOI: 10.1039/c4cp03994g
Haies, I. M., Jarvis, J. A., Brown, L. J., Kuprov, I., Williamson, P. T. F., & Carravetta, M. (2015). 14N overtone transition in double rotation solid-state NMR. Physical Chemistry Chemical Physics, 17(37), 23748-23753. DOI: 10.1039/C5CP03266K
Fox, S. J., Gourdain, S., Coulthurst, A., Fox, C., Kuprov, I., Essex, J. W., ... Linclau, B. (2015). A computational study of vicinal fluorination in 2,3-difluorobutane: implications for conformational control in alkane chains. Chemistry - A European Journal, 21, 1682-1691. DOI: 10.1002/chem.201405317
Kuprov, I., Hodgson, D. M., Kloesges, J., Pearson, C. I., Odell, B., & Claridge, T. D. W. (2015). Anomalous nuclear overhauser effects in carbon-substituted aziridines: scalar cross-relaxation of the first kind. Angewandte Chemie International Edition, 54(12), 3697-3701. DOI: 10.1002/anie.201410271
Goodwin, D., & Kuprov, I. (2015). Auxiliary matrix formalism for interaction representation transformations, optimal control, and spin relaxation theories. Journal of Chemical Physics, 143(8), 1-7. DOI: 10.1063/1.4928978
Kolmer, A., Edwards, L. J., Kuprov, I., & Thiele, C. M. (2015). Conformational analysis of small organic molecules using NOE and RDC data: A discussion of strychnine and a-methylene-y-butyrolactone. Journal of Magnetic Resonance, 261, 101-109. DOI: 10.1016/j.jmr.2015.10.007
Stevanato, G., Singha Roy, S., Hill-Cousins, J., Kuprov, I., Brown, L. J., Brown, R., ... Levitt, M. H. (2015). Long-lived nuclear spin states far from magnetic equivalence. Physical Chemistry Chemical Physics, 1-11. DOI: 10.1039/C4CP05704J
Glaser, S. J., Boscain, U., Calarco, T., Koch, C. P., Köckenberger, W., Kosloff, R., ... Wilhelm, F. K. (2015). Training Schrödinger’s cat: quantum optimal control. The European Physical Journal D, 69(12), 1-24. DOI: 10.1140/epjd/e2015-60464-1
Gouilleux, B., Rouger, L., Charrier, B., Kuprov, I., Akoka, S., Dumez, J-N., & Giraudeau, P. (2015). Understanding J-modulation during spatial encoding for sensitivity-optimized ultrafast NMR spectroscopy. ChemPhysChem, 16(14), 3093-3100. DOI: 10.1002/cphc.201500514
Charnock, G. T. P., & Kuprov, I. (2014). A partial differential equation for pseudocontact shift. Physical Chemistry Chemical Physics, 16(37), 20184-20189. DOI: 10.1039/C4CP03106G
Biternas, A. G., Charnock, G. T. P., & Kuprov, I. (2014). A standard format and a graphical user interface for spin system specification. Journal of Magnetic Resonance, 240, 124-131. DOI: 10.1016/j.jmr.2014.01.004
Savostyanov, D. V., Dolgov, S. V., Werner, J. M., & Kuprov, I. (2014). Exact NMR simulation of protein-size spin systems using tensor train formalism. Physical Review B, 90(8), [085139]. DOI: 10.1103/PhysRevB.90.085139
Edwards, L. J., Savostyanov, D. V., Welderufael, Z. T., Lee, D., & Kuprov, I. (2014). Quantum mechanical NMR simulation algorithm for protein-size spin systems. Journal of Magnetic Resonance, 243, 107-113. DOI: 10.1016/j.jmr.2014.04.002
Edwards, L. J., Savostyanov, D. V., Nevzorov, A. A., Concistrè, M., Pileio, G., & Kuprov, I. (2013). Grid-free powder averages: on the applications of the Fokker–Planck equation to solid state NMR. Journal of Magnetic Resonance, 235, 121-129. DOI: 10.1016/j.jmr.2013.07.011
Mamone, S., Concistrè, M., Heinmaa, I., Carravetta, M., Kuprov, I., Wall, G., ... Levitt, M. H. (2013). Nuclear magnetic resonance of hydrogen molecules trapped inside C70 fullerene cages. ChemPhysChem, 14(13), 3121-3130. DOI: 10.1002/cphc.201300269
Kuprov, I. (2013). Spin system trajectory analysis under optimal control pulses. Journal of Magnetic Resonance. DOI: 10.1016/j.jmr.2013.02.012
Pileio, G., Hill-Cousins, J. T., Mitchell, S., Kuprov, I., Brown, L. J., Brown, R. C. D., & Levitt, M. H. (2012). Long-lived nuclear singlet order in near-equivalent 13c spin pairs. Journal of the American Chemical Society, 134(42), 17494-17497. DOI: 10.1021/ja3089873
Charnock, G. T. P., Krzystyniak, M., & Kuprov, I. (2012). Molecular structure refinement by direct fitting of atomic coordinates to experimental ESR spectra. Journal of Magnetic Resonance, 216, 62-68. DOI: 10.1016/j.jmr.2012.01.003
Edwards, L. J., & Kuprov, I. (2012). Parallel density matrix propagation in spin dynamics simulations. The Journal of Chemical Physics, 136(4), 44108. DOI: 10.1063/1.3679656
Karabanov, A., van der Drift, A., Edwards, L. J., Kuprov, I., & Köckenberger, W. (2012). Quantum mechanical simulation of solid effect dynamic nuclear polarisation using Krylov–Bogolyubov time averaging and a restricted state-space. Physical Chemistry Chemical Physics, 14(8), 2658-2668. DOI: 10.1039/C2CP23233B
Krzystyniak, M., Edwards, L. J., & Kuprov, I. (2011). Destination state screening of active spaces in spin dynamics simulations. Journal of Magnetic Resonance, 210(2), 228-232. DOI: 10.1016/j.jmr.2011.03.010
Kuprov, I. (2011). Diagonalization-free implementation of spin relaxation theory for large spin systems. Journal of Magnetic Resonance, 209(1), 31-38. DOI: 10.1016/j.jmr.2010.12.004
Dias, D. M., Teixeira, J. M. C., Kuprov, I., New, E. J., Parker, D., & Geraldes, C. F. G. C. (2011). Enantioselective binding of a lanthanide(iii) complex to human serum albumin studied by 1H STD NMR techniques. Organic & Biomolecular Chemistry, 9(14), 5047-5050. DOI: 10.1039/C1OB05524K
Harvey, P., Kuprov, I., & Parker, D. (2011). Lanthanide complexes as paramagnetic probes for 19F magnetic resonance. European Journal of Inorganic Chemistry, 2012(12), 2015-2022. DOI: 10.1002/ejic.201100894
Auer, R., Tollinger, M., Kuprov, I., Konrat, R., & Kloiber, K. (2011). Mathematical treatment of adiabatic fast passage pulses for the computation of nuclear spin relaxation rates in proteins with conformational exchange. Journal of Biomolecular NMR, 51(1-2), 35-47. DOI: 10.1007/s10858-011-9539-8
Hogben, H. J., Hore, P. J., & Kuprov, I. (2011). Multiple decoherence-free states in multi-spin systems. Journal of Magnetic Resonance, 211(2), 217-220. DOI: 10.1016/j.jmr.2011.06.001
Karabanov, A., Kuprov, I., Charnock, G. T. P., van der Drift, A., Edwards, L. J., & Köckenberger, W. (2011). On the accuracy of the state space restriction approximation for spin dynamics simulations. The Journal of Chemical Physics, 135(8), 084106-[8 pages]. DOI: 10.1063/1.3624564
de Fouquieres, P., Schirmer, S. G., Glaser, S. J., & Kuprov, I. (2011). Second order gradient ascent pulse engineering. Journal of Magnetic Resonance, 212(2), 412-417. DOI: 10.1016/j.jmr.2011.07.023
Hogben, H. J., Krzystyniak, M., Charnock, G. T. P., Hore, P. J., & Kuprov, I. (2011). Spinach – a software library for simulation of spin dynamics in large spin systems. Journal of Magnetic Resonance, 208(2), 179-194. DOI: 10.1016/j.jmr.2010.11.008
Kummerlöwe, G., Grage, S. L., Thiele, C. M., Kuprov, I., Ulrich, A. S., & Luy, B. (2011). Variable angle NMR spectroscopy and its application to the measurement of residual chemical shift anisotropy. Journal of Magnetic Resonance, 209(1), 19-30. DOI: 10.1016/j.jmr.2010.11.019
Senthamarai, R. R. P., Kuprov, I., & Pervushin, K. (2010). Benchmarking NMR experiments: a relational database of protein pulse sequences. Journal of Magnetic Resonance, 203(1), 129-137. DOI: 10.1016/j.jmr.2009.12.008
Chalmers, K. H., De Luca, E., Hogg, N. H. M., Kenwright, A. M., Kuprov, I., Parker, D., ... Blamire, A. M. (2010). Design principles and theory of paramagnetic fluorine-labelled lanthanide complexes as probes for19F magnetic resonance: a proof-of-concept study. Chemistry - A European Journal, 16(1), 134-148. DOI: 10.1002/chem.200902300
Santabarbara, S., Kuprov, I., Poluektov, O., Casal, A., Russell, C. A., Purton, S., & Evans, M. C. W. (2010). Directionality of electron-transfer reactions in photosystem I of prokaryotes: universality of the bidirectional electron-transfer model. The Journal of Physical Chemistry B, 114(46), 15158-15171. DOI: 10.1021/jp1044018
Natrajan, L. S., Khoabane, N. M., Dadds, B. L., Muryn, C. A., Pritchard, R. G., Heath, S. L., ... Faulkner, S. (2010). Probing the structure, conformation, and stereochemical exchange in a family of lanthanide complexes derived from tetrapyridyl-appended cyclen. Inorganic Chemistry, 49(17), 7700-7709. DOI: 10.1021/ic100447m
Hogben, H. J., Hore, P. J., & Kuprov, I. (2010). Strategies for state space restriction in densely coupled spin systems with applications to spin chemistry. The Journal of Chemical Physics, 132(17), 174101-[10 pages]. DOI: 10.1063/1.3398146
Kuprov, I., & Rodgers, C. T. (2009). Derivatives of spin dynamics simulations. The Journal of Chemical Physics, 131(23), 234108-[8 pages]. DOI: 10.1063/1.3267086
Kenwright, A. M., Kuprov, I., De Luca, E., Parker, D., Pandya, S. U., Senanayake, P. K., & Smith, D. G. (2008). 19F NMR based pH probes: lanthanide(iii) complexes with pH-sensitive chemical shifts. Chemical Communications, (22), 2514-2516. DOI: 10.1039/B802838A
Maeda, K., Henbest, K. B., Cintolesi, F., Kuprov, I., Rodgers, C. T., Liddell, P. A., ... Hore, P. J. (2008). Chemical compass model of avian magnetoreception. Nature, 453(7193), 387-390. DOI: 10.1038/nature06834
Kuprov, I. (2008). Polynomially scaling spin dynamics II: further state-space compression using Krylov subspace techniques and zero track elimination. Journal of Magnetic Resonance, 195(1), 45-51. DOI: 10.1016/j.jmr.2008.08.008
Kuprov, I., Wagner-Rundell, N., & Hore, P. J. (2007). Bloch-Redfield-Wangsness theory engine implementation using symbolic processing software. Journal of Magnetic Resonance, 184(2), 196-206. DOI: 10.1016/j.jmr.2006.09.023
Kuprov, I., Wagner-Rundell, N., & Hore, P. J. (2007). Polynomially scaling spin dynamics simulation algorithm based on adaptive state-space restriction. Journal of Magnetic Resonance, 189(2), 241-250. DOI: 10.1016/j.jmr.2007.09.014
Kuprov, I., Craggs, T. D., Jackson, S. E., & Hore, P. J. (2007). Spin relaxation effects in photochemically induced dynamic nuclear polarization spectroscopy of nuclei with strongly anisotropic hyperfine couplings. Journal of the American Chemical Society, 129(29), 9004-9013. DOI: 10.1021/ja0705792
Khan, F., Kuprov, I., Craggs, T. D., Hore, P. J., & Jackson, S. E. (2006). 19F NMR studies of the native and denatured states of green fluorescent protein. Journal of the American Chemical Society, 128(33), 10729-10737. DOI: 10.1021/ja060618u
Santabarbara, S., Kuprov, I., Hore, P. J., Casal, A., Heathcote, P., & Evans, M. C. W. (2006). Analysis of the spin-polarized electron spin echo of the [P700+A1-] radical pair of photosystem I indicates that both reaction center subunits are competent in electron transfer in cyanobacteria, green algae, and higher plants. Biochemistry, 45(23), 7389-7403. DOI: 10.1021/bi060330h
van Thor, J. J., Mackeen, M., Kuprov, I., Dwek, R. A., & Wormald, M. R. (2006). Chromophore structure in the photocycle of the cyanobacterial phytochrome Cph1. Biophysical Journal, 91(5), 1811-1822. DOI: 10.1529/biophysj.106.084335
Goez, M., Kuprov, I., Hun Mok, K., & Hore, P. J. (2006). Novel pulse sequences for time-resolved photo-CIDNP. Molecular Physics, 104(10-11), 1675-1686. DOI: 10.1080/00268970600634431
Henbest, K. B., Athanassiades, E., Maeda, K., Kuprov, I., Hore, P. J., & Timmel, C. R. (2006). Photoionization of TMPD in DMSO solution: mechanism and magnetic field effects. Molecular Physics, 104(10-11), 1789-1794. DOI: 10.1080/00268970600611017
Santabarbara, S., Kuprov, I., Fairclough, W. V., Purton, S., Hore, P. J., Heathcote, P., & Evans, M. C. W. (2005). Bidirectional electron transfer in photosystem I: determination of two distances between P700+ and A1- in spin-correlated radical pairs. Biochemistry, 44(6), 2119-2128. DOI: 10.1021/bi048445d
Kuprov, I., Goez, M., Abbott, P. A., & Hore, P. J. (2005). Design and performance of a microsecond time-resolved photo-chemically induced dynamic nuclear polarization add-on for a high-field nuclear magnetic resonance spectrometer. Review of Scientific Instruments, 76(8), 084103-[7pp]. DOI: 10.1063/1.2010287
Goez, M., Kuprov, I., & Hore, P. J. (2005). Increasing the sensitivity of time-resolved photo-CIDNP experiments by multiple laser flashes and temporary storage in the rotating frame. Journal of Magnetic Resonance, 177(1), 139-145. DOI: 10.1016/j.jmr.2005.06.017
Kuprov, I., & Hore, P. J. (2004). Chemically amplified 19F–1H nuclear Overhauser effects. Journal of Magnetic Resonance, 168(1), 1-7. DOI: 10.1016/j.jmr.2004.01.011
Kuprov, I., & Hore, P. J. (2004). Uniform illumination of optically dense NMR samples. Journal of Magnetic Resonance, 171(1), 171-175. DOI: 10.1016/j.jmr.2004.08.017

Conferences

Saywell, J. C., Carey, M. S., Elcock, D. E., Belal, M., Kuprov, I., & Freegarde, T. (2018). Optimal pulses for enhanced interferometer sensitivity and contrast. Poster session presented at Frontiers in Matter Wave Optics, Crete, Greece.
Raybould, T. A., Fedotov, V. A., Papasimakis, N., Kuprov, I., Youngs, I., Chen, W. T., ... Zheludev, N. I. (2015). Chiral phenomena in toroidal metamaterials. Paper presented at 9th International Congress on Advanced Electromagnetic Materials in Microwaves and Optics - Metamaterials 2015, United Kingdom.

Ilya Kuprov's Publications and Citation Metrics

Dr Ilya Kuprov
Chemistry University of Southampton Highfield Southampton SO17 1BJ

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