The University of Southampton
Courses

CHEM2022 Intermediate Inorganic Chemistry I

Module Overview

Aims and Objectives

Module Aims

The aim of this module is to provide a basis for future studies in chemistry and allied subjects. Students select two areas of Chemistry from Inorganic, Organic, and Physical Chemistry according to the needs of their programme of study. More specific aims, content and learning outcomes are provided under each of the headings of inorganic, organic, and physical chemistry. Please consult with the leader of your programme or your personal academic tutor in deciding which two components of this module to follow.

Learning Outcomes

Learning Outcomes

Having successfully completed this module you will be able to:

  • Use group theory to determine the symmetry of vibrational and bonding modes in molecules
  • Explain the main features of electronic spectra
  • Construct bonding models for multi-atomic molecules
  • Explain the fundamentals of X-ray diffraction and process powder X-ray diffraction data collected on high symmetry (cubic) structures
  • Use the properties of transition metals and ligands to explain structures and basic properties of transition metal complexes
  • Discuss the main reaction mechanisms that operate in transition metal complexes

Syllabus

• Elementary aspects of group theory. • UV-visible spectroscopy including Russell-Saunders, Orgel diagrams and magnetism. • Revision of relevant synoptic material; d orbitals, oxidation states,dn configurations, ligand donor/acceptor properties, spectrochemical series, coordination geometries, CFSE. • Ligand field theory. • Ligand types including architecture and steric/electronic effects: carbonyl, phosphines, N2 and NO. • MO bonding in octahedral ML6 complexes - σ and π-bonding. • Chemistry of the 4d and 5d elements. Metal-metal bonding. • Brief revision of unit cells and lattices. • Basis of X-ray diffraction: Bragg’s law, powder XRD, instrumentation, applications.

Learning and Teaching

Teaching and learning methods

Lectures, problem-solving classes, tutorials and workshops, with group working and tutor support Workshop hours includes 4 hours of problem classes. Preparation for scheduled sessions hours includes other independent study.

TypeHours
Lecture24
Revision10
Preparation for scheduled sessions31
Workshops6
Tutorial4
Total study time75

Resources & Reading list

Housecroft and Sharpe. Inorganic Chemistry. 

Ogden. Introduction to Molecular Symmetry. 

Brisdon. Inorganic Spectroscopic Methods. 

Assessment

Assessment Strategy

The practical and theory (examination plus tutorial) components must be passed separately at the module pass mark for the student’s programme, i.e. 40% if core, 25% if compulsory or optional (if compensation is allowed). All absences from practical sessions must be validated and unexcused absences will result in failure of the module..

Summative

MethodPercentage contribution
Assessed Tutorials 10%
Examination  (2 hours) 90%

Referral

MethodPercentage contribution
Examination  (2 hours) 100%

Repeat Information

Repeat type: Internal & External

Linked modules

CHEM1036 or CHEM1046

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